The 3D Graphene Foam is deposited comformably onto Nickel foam foils by chemical vapor deposition (CVD) process. Nickel (Ni) foams were created by acid reaction at high temperatures, followed by 4-step CVD graphene growth process. Overall, few-layers and single-layers of graphene is deposited onto Ni walls after reacting C2H4 gas with H2 gases. These materials are ideal for gas separation, catalysis, gas detection, sensory applications.